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Hcn Molecular Geometry – HCN (Hydrogen cyanide) Molecular Geometry & Bond Angles

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Introduce about HCN (Hydrogen cyanide) Molecular Geometry & Bond Angles

An explanation of the molecular geometry for the HCN ion (Hydrogen cyanide) including a description of the HCN bond angles. The electron geometry for the Hydrogen cyanide is also provided.

The ideal bond angle for the Hydrogen cyanide is 180° since it has a Linear molecular geometry. Experimentally we would expect the bond angle to be approximately 180°.

To determine the molecular geometry, or shape for a compound like HCN, we complete the following steps:

1) Draw the Lewis Structure for the compound.
2) Predict how the atoms and lone pairs will spread out when the repel each other.
3) Use a chart based on steric number (like the one in the video) or use the AXN notation to find the molecular shape. This will be determined by the number of atoms and lone pairs attached to the central atom.
If you are trying to find the electron geometry for HCN we would expect it to be Linear.

Helpful Resources:

• How to Draw Lewis Structures:
• Molecular Geometry and VSEPR Explained:
• Molecular Geo App:
Get more chemistry help at

Drawing/writing done in InkScape. Screen capture done with Camtasia Studio 4.0. Done on a Dell Dimension laptop computer with a Wacom digital tablet (Bamboo).

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